Nuclear Waste Management

Nuclear energy harnesses the energy released during the splitting or
fusing of atomic nuclei. This heat energy is most often used to convert water
to steam, turning turbines, and generating electricity.
However, nuclear energy also has many disadvantages. An event that
demonstrated this was the terrible incident at Chernobyl'. Here on April 26,
1986, one of the reactors of a nuclear power plant went out of control and
caused the world's worst known reactor disaster to date. An experiment that was
not properly supervised was conducted with the water-cooling system turned off.
This led to the uncontrolled reaction, which in turn caused a steam explosion.
The reactor's protective covering was blown off, and approximately 100 million
curies of radionuclides were released into the atmosphere. Some of the
radiation spread across northern Europe and into Great Britain. Soviet
statements indicated that 31 people died because of the accident, but the number
of radiation-caused deaths is still unknown.
The same deadly radiation that was present in this explosion is also
present in spent fuels. This presents special problems in the handling, storage,
and disposal of the depleted uranium. When nuclear fuel is first loaded into a
reactor, 238U and 235U are present. When in the reactor, the 235U is gradually
depleted and gives rise to fission products, generally, cesium (137Cs) and
strontium (90Sr). These waste materials are very unstable and have to undergo
radioactive disintegration before they can be transformed into stable isotopes.
Each radioactive isotope in this waste material decays at its characteristic
rate. A half-life can be less than a second or can be thousands of years long.
The isotopes also emit characteristic radiation: it can be electromagnetic (X-
ray or gamma radiation) or it can consist of particles (alpha, beta, or neutron
Exposure to large doses of ionizing radiation causes characteristic
patterns of injury. Doses are measured in rads (1 rad is equal to an amount of
radiation that releases 100 ergs of energy per gram of matter). Doses of more
than 4000 rads severely damage the human vascular system, causing cerebral edema
(excess fluid), which leads to extreme shock and neurological disturbances
causing death within 48 hours. Whole-body doses of 1000 to 4000 rads cause less
severe vascular damage, but they can lead to a loss of fluids and electrolytes
into the intercellular spaces and the gastrointestinal tract causing death
within ten days because of a fluid and electrolyte imbalance, severe bone-marrow
damage, and terminal infection. Absorbed doses of 150 to 1000 rads cause
destruction of human bone marrow, leading to infection and hemorrhage death may
occur after four to five weeks after the date of exposure. Currently only the
effects of these lower doses can be treated effectively, but if untreated, half
the perso ns receiving as little as 300 to 325 rads to the bone marrow will die.
To store the nuclear waste products that give off this deadly radiation,
many precautions must be taken. Spent fuel may be stored or solidified.
The primary way of storing the nuclear waste is storage. Since spent
fuel continues to be a source of heat and radiation after it is taken from the
reactor, it can be stored underwater in a deep pool at the reactor site. The
water keeps the fuel assemblies cool and acts as a shield to protect workers
from gamma radiation. The water is kept free of minerals that would corrode the
fuel in tubes.
Fuel assemblies are kept separated in the pool by metal racks that leave
one foot between centers. This grid structure is made with metal containing
boron, which helps to absorb neutrons and prevents their multiplication.
A problem with this type of storage is that in 1977, a federal
moratorium on reprocessing was instituted. This required the utility companies
to keep used fuel at the reactor site. This requirement was met by building
closer-packed racks to store more fuel in the same amount of space.
An alternative way of storing spent fuel is through solidification.
Federal regulations require that liquid reprocessing waste be solidified for
disposal within five years of production. There are different approaches to
solidification. These include calcination, vitrification, and incorporation of
waste into ceramics and synthetic materials. Calcination is a process in which
the liquid waste is sprayed through an atomizer and then dried at a high
temperature. This results in ?calcine? (which is highly radioactive) and
temporarily stored in bins for further processing.
Vitrification consists of the mixing of calcined waste with borosilicate
glass grit. This is melted in a specialized furnace and cast into a mold.
Borosilicate glass is considered a suitable matrix for nuclear waste because the
glass has strong interatomic bonding but not a strict atomic structure. Because
of this, it is able to